1)

When acetylene is passed into methanol at 160- 200°C in the presence of a small amount of potassium methoxide under pressure, the following is formed -


A) Polyvinyl alcohol

B) Divinyl ether

C) Dimethyl ether

D) Methyl vinyl ether

Answer:

Option D

Explanation:

When acetylene is passed into methanol at 160-200°C in the presence of a small amount (1-2%) of potassium methoxide and under pressure just high enough to prevent boiling, methyl vinyl ether is formed. The mechanism is believed to involve nucleophildic attack in the first step.

 1932021811_chemistry76.JPG